Do flat sealing rings have good resistance to ozone?

Dec 12, 2025

As a supplier specializing in flat sealing rings, I often encounter inquiries regarding the performance of these products under various environmental conditions. One such critical inquiry revolves around the resistance of flat sealing rings to ozone. Ozone, a highly reactive gas present in the Earth's atmosphere, can have detrimental effects on many types of materials, potentially compromising the integrity and functionality of sealing rings. In this blog, we will explore the ozone resistance of flat sealing rings, delving into the factors that influence it and the materials commonly used to ensure optimal performance.

Understanding Ozone and Its Impact on Sealing Rings

Ozone is a triatomic form of oxygen (O₃) that is naturally present in the stratosphere, where it plays a crucial role in protecting the Earth from harmful ultraviolet radiation. However, at ground - level, ozone can be a pollutant, formed through chemical reactions between nitrogen oxides (NOₓ) and volatile organic compounds (VOCs) in the presence of sunlight. Ground - level ozone is a strong oxidizing agent, capable of reacting with a wide range of materials, including polymers commonly used in sealing rings.

When a flat sealing ring is exposed to ozone, the ozone molecules can react with double bonds in the polymer chains of the sealing material. This reaction can cause chain scission, cross - linking, or the formation of new chemical groups, leading to changes in the physical and mechanical properties of the sealing ring. These changes can manifest as cracking, hardening, or loss of elasticity, which can ultimately result in seal failure, leakage, and reduced equipment performance.

Factors Affecting Ozone Resistance of Flat Sealing Rings

Several factors influence the ozone resistance of flat sealing rings. The most significant factor is the type of material used in the manufacturing of the ring. Different polymers have varying degrees of resistance to ozone, depending on their chemical structure and composition.

  • Polymer Structure: Polymers with fewer double bonds in their molecular structure are generally more resistant to ozone. For example, fully saturated polymers such as ethylene - propylene - diene monomer (EPDM) and fluorocarbon elastomers (FKM) have excellent ozone resistance because they lack the reactive double bonds that ozone can attack.
  • Additives: The addition of antioxidants and antiozonants to the polymer formulation can significantly enhance the ozone resistance of flat sealing rings. These additives work by reacting with ozone molecules before they can react with the polymer chains, thus protecting the integrity of the sealing material.
  • Exposure Conditions: The concentration of ozone, temperature, and duration of exposure also play a crucial role in determining the ozone resistance of flat sealing rings. Higher ozone concentrations, elevated temperatures, and longer exposure times can accelerate the degradation process, reducing the lifespan of the sealing ring.

Materials with Good Ozone Resistance for Flat Sealing Rings

As a supplier, we offer a range of flat sealing rings made from different materials, each with its own unique properties and ozone resistance characteristics.

  • EPDM Flat Sealing Rings: EPDM is a synthetic rubber known for its outstanding resistance to ozone, weathering, and aging. It has a fully saturated polymer backbone, which makes it highly resistant to ozone attack. EPDM flat sealing rings are commonly used in outdoor applications, such as in automotive weatherstripping, roofing systems, and outdoor electrical enclosures, where they are exposed to high levels of ozone and other environmental factors.

  • FKM Flat Sealing Rings: Fluorocarbon elastomers (FKM), also known as Viton®, are another group of materials with excellent ozone resistance. FKM has a high fluorine content, which provides it with superior chemical resistance, thermal stability, and ozone resistance. FKM flat sealing rings are widely used in industries such as aerospace, automotive, and chemical processing, where they are exposed to harsh chemicals, high temperatures, and ozone - rich environments.

  • HNBR Flat Sealing Ring Black: Hydrogenated nitrile butadiene rubber (HNBR) is a specialty elastomer that offers a good balance of mechanical properties and chemical resistance. HNBR has excellent ozone resistance compared to traditional nitrile rubber (NBR). The HNBR Flat Sealing Ring Black is suitable for applications where high - performance sealing is required in the presence of ozone and other aggressive chemicals.

Case Studies: Real - World Applications

To illustrate the importance of ozone resistance in flat sealing rings, let's consider a couple of real - world examples:

  • Automotive Industry: In automotive applications, flat sealing rings are used in various components, such as engine gaskets, transmission seals, and fuel system seals. These seals are often exposed to ozone in the atmosphere, as well as to heat and chemicals generated by the engine. Using ozone - resistant materials like EPDM or HNBR in these seals can significantly extend their service life, reducing the risk of leakage and improving the overall reliability of the vehicle.

    NBR Flat Sealing Ring Black 02NBR Flat Sealing Ring Black 03

  • Electrical Industry: In electrical enclosures, flat sealing rings are used to provide a watertight and airtight seal, protecting the electrical components from dust, moisture, and ozone. EPDM flat sealing rings, with their excellent ozone resistance and weatherability, are a popular choice for these applications. By using high - quality, ozone - resistant sealing rings, electrical equipment manufacturers can ensure the long - term performance and safety of their products.

Comparing Ozone Resistance of Different Nitrile - Based Flat Sealing Rings

It is also essential to understand the differences in ozone resistance between different nitrile - based flat sealing rings.

  • NBR Flat Sealing Ring: Nitrile butadiene rubber (NBR) is a common elastomer used in sealing applications. However, NBR has limited ozone resistance due to the presence of double bonds in its polymer structure. NBR flat sealing rings are typically used in applications where ozone exposure is minimal, such as in oil - lubricated systems or industrial machinery where the sealing environment is relatively controlled.

  • NBR Flat Sealing Ring Black: The black version of NBR flat sealing rings often contains carbon black, which can provide some additional protection against ozone to a certain extent. But still, its ozone resistance is not as good as that of EPDM, FKM, or HNBR.

Conclusion and Call to Action

In conclusion, flat sealing rings can have varying degrees of ozone resistance depending on the material they are made of. Materials such as EPDM, FKM, and HNBR offer excellent ozone resistance and are suitable for applications where exposure to ozone is a concern. As a supplier, we are committed to providing high - quality flat sealing rings that meet the specific requirements of our customers, including ozone resistance.

If you are in need of flat sealing rings with good ozone resistance for your application, we invite you to contact us for more information. Our team of experts can help you select the most appropriate material and design for your sealing needs. Whether you are working on an automotive project, an electrical application, or any other industry that requires reliable sealing solutions, we have the products and expertise to support you. Let's start a conversation about your sealing requirements and find the best flat sealing ring solution together.

References

  • "Elastomers and Rubber Compounding Materials" by Werner Hofmann
  • "Handbook of Seal Materials and Technology" edited by David D. Dowson and Michael Godfrey
  • "Ozone Degradation of Polymers" in the Journal of Polymer Science: Part A: Polymer Chemistry